From Chapter 1:
So far Hariot's "Report" regarded tobacco from the medicinal point of view only; but it is important to note that he goes on to describe his personal experience of the practice of smoking in words that suggest the pleasurable nature of the experience. He says: "We ourselves during the time we were there used to suck it after their maner, as also since our returne, and have found maine [? manie] rare and wonderful experiments of the vertues thereof: of which the relation woulde require a volume by itselfe: the use of it by so manie of late, men and women of great calling as else, and some learned Physitians also, is sufficient witness."

From Chapter 3:
Sometimes coltsfoot was mixed with tobacco. Ursula, the pig-woman and refreshment-booth keeper in Bartholomew Fair, in Ben Jonson's play of that name, says to her assistant: "Threepence a pipe-full I will have made, of all my whole half-pound of tobacco and a quarter of a pound of coltsfoot mixt with it too to eke it out."

From Chapter 1:
Every one knows the legend of the water (or beer) thrown over Sir Walter by his servant when he first saw his master smoking, and imagined he was on fire. The story was first associated with Raleigh by a writer in 1708 in a magazine called the British Apollo. According to this yarn Sir Walter usually "indulged himself in Smoaking secretly, two pipes a Day; at which time, he order'd a Simple Fellow, who waited, to bring him up a Tankard of old Ale and Nutmeg, always laying aside the Pipe, when he heard his servant coming." On this particular occasion, however, the pipe was not laid aside in time, and the "Simple Fellow," imagining his master was on fire, as he saw the smoke issuing from his mouth, promptly put the fire out by sousing him with the contents of the tankard. One difficulty about this story is the alleged secrecy of Raleigh's indulgence in tobacco. There seems to be no imaginable reason why he should not have smoked openly. Later versions turn the ale into water and otherwise vary the story.

From Chapter 1:
Another Elizabethan who is often said to have smoked the first pipe in England is Ralph Lane, the first Governor of Virginia, who came home with Drake in 1586. Lane is said to have given Sir Walter Raleigh an Indian pipe and to have shown him how to use it. There is no original authority, however, for the statement that Lane first smoked tobacco in England, and, moreover, he was not the first English visitor to Virginia to return to this country. One Captain Philip Amadas accompanied Captain Barlow, who commanded on the occasion of Raleigh's first voyage of discovery, when the country was formally taken possession of and named Virginia in honour of Queen Elizabeth. This was early in 1584. The two captains reached England in September 1584, bringing with them the natives of whom King James I, in his "Counter-blaste to Tobacco," speaks as "some two or three Savage men," who "were brought in, together with this Savage custome," i.e. of smoking. It is extremely improbable that Captains Amadas and Barlow, when reporting to Raleigh on their expedition, did not also make him acquainted with the Indian practice of smoking. This would be two years before the return of Ralph Lane.